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Activated
Bleaching Earth
AMC
(UK) ltd are the sole distributors for a wide range
of high quality “Fulmont” bleaching earths produced
by Rockwood additives Ltd.
Representing
more than 50 years of Fulmont bleaching earth
production AMC UK Ltd offers an extensive
range of acid-activated products including natural bleaching
earth.
PRODUCT
& GRADES
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Fulmont
Bleaching Earth |
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Fulmont
Product Development |
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Fulmont
Quality Assurance |
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Fulmont
Environmental Awareness |
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Fulmont
Bleaching Earths |
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| Oil
or Fat Type |
Bleaching
Demand |
| Easy |
Normal |
Challenging |
Difficult |
Speciality
Oils
Sunflower, Safflower
Oleins, Cottonseed |
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Soya,
Rape, Palm, Animal Fats,
Coconut, Hydrogenated Fats, Waxes
Linseed, Castor, Palm Stearine |
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High
Colour Oxidised Crude Oils
eg. Rape, Palm, Tallow, Rice Bran |
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Grade |
Fulmont
"AA" |
Fulmont
Premiere |
Fulmont
XMP-3 |
Fulmont
XMP-4 |
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Fulmont
- Uses |
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THE
REFINING PROCESSES
Traditionally,
acid-activated clays have found widespread use in the global
edible oil and fats refining industry. Both edible vegetable
oils and animal fats are refined using montmorillonite clay
that has been activated with mineral acid.
Origin
of clay use
Bleaching
earth, known also as Bentonite and Fullers Earth, has been
used for many centuries - originally in Roman times for cleaning
sheep fleeces, a process known as fulling. In modern times,
bentonite clay of the type calcium montmorillonite was found
to have special properties due to its large surface area -
which could be increased by acid activation. Today’s
manufacturers produce clays ranging from natural, through
to fully acid-activated clays.
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oil refining processes |
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| Neutralised
and bleached storage |
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The
edible oil / fats refining process
The growth
of the acid-activated bleaching earth market began in the
1950’s. There was an increasing requirement for more
highly activated products, due to the requirement for much
paler coloured cooking oils. Previously, most edible oils
and fats were caustic refined [Chemical refining], involving
several water-washing steps to remove the soap stock. Before
the final step of deodorisation could take place, any residual
soap had to be completely removed using bleaching clay. The
clay was not highly acid activated since soap removal rather
than colour removal was the priority.
The requirement
for pale-coloured edible oils along with advancement in edible
oil processing technology meant that many oils could be processed
without the use of caustic, thus obviating the need for chemical
refining and the subsequent water-washing centrifuges - with
considerable associated cost reduction.
The process
of refining oil without the use of caustic is commonly referred
to as “physical refining” which represents the
most popular method of refining today.
In the
physical refining process, impurity removal and bleaching
falls solely to the activated bleaching earth. Acid-activated
clays are now required to remove trace metals, oxidation products,
phosphatides, pigments and their breakdown products. When
utilised correctly, bleaching clay produces a stable pale
yellow coloured oil/fat which is resistant to oxidation.
Global
oils & Fats
The global
edible oil and fats economy revolves principally around 17
oils and fats. Of these, the most important are soyabean oil,
rapeseed oil, sunflower oil, palm oil and maize oil. Lauric
fats such as coconut or palm kernel oil are also of importance,
but their production is on a much smaller scale. Across Europe,
the most important oils are soyabean, rapeseed and palm.
In addition
bleaching earths are used in various alternative applications,
including:
- Paraffin
and waxes used in the food industry
- Waste
oils regenerated from the refining of lubricating oils
- Rolling
oils used as lubricants
- Mineral
oils for special applications, including transformer oils
- Turbine
oils and medicinal white oils
- Industrial
triglycerides used in paint manufacture, including varnishes
and soaps
- Solvents
used in the dry cleaning industry, i.e. hydrocarbons
- Bleaching
of mined sulphur, where the bleaching earth is used to remove
bituminous products.
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BLEACHING
OF EDIBLE OILS AND FATS |
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The
overall in-use efficiency of bleaching earth is
determined by several parameters, namely:
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Adsorption capacity
• Catalytic properties
• Ion exchange capacity
• Acid properties
• Particle size distribution.
Adsorption:
The
high adsorption capacity of bleaching earths is
their best-known property and adsorption capacity
can be enhanced with acid treatment. The resultant
increases in pore volume and surface area enhance
the above parameters, giving the bleaching earth
a high adsorption capacity for phosphatides, colouring
pigments and trace metal impurities.
Catalytic
properties:
The
catalytic properties of the clay, are responsible
for the destruction of peroxides, which increases
oxidation stability of the refined oil
Particle size distribution & filtration:
The
particle size distribution is of crucial importance:
poor granulometry can lead to poor filtration
rates and bleaching underperformance. It is thus
essential to have tight control of particle size
distribution in order to optimize overall bleaching
efficiency. It is important to note that different
oils and fats may require different bleaching
earth characteristics. Fulmont provides an optimized
particle size distribution.
A
Fulmont fully acid-activated
product ensures rapid filtration and may well
exhibit bleaching activity 20 - 40% above that
normally seen leading to a potential reduction
in dosage requirements.
AMC supply a comprehensive range
of bleaching earths for most applications required
today.
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SPENT
BLEACHING EARTH DISPSAL |
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Spent
bleaching earth is disposed to:
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Landfill: Consult your local
government for disposal criteria.
• Incineration: Whilst
a more useful solution, it is far more costly.
However, in some countries, where disposal to
landfill has become increasingly difficult, the
incineration route has become more popular.
Regeneration
The quality of the recovered clay is generally
poor and too variable to be considered for commercial
applications in the edible oils and fats industry.
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MARKET
OVERVIEW
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| Figure
3.1: Development of 17 Oils/Fats Production
[million tonnes] |
![PRODUCTION OF OILS AND FATS
Over the last 50 years there have been significant changes to food production and processing with a trend away from animal fats towards [healthier] vegetable oils. The changes have been reflected by large scale production of oilseeds and improved processing technology.](images/bleaching_earth/graph_3_1.gif) |
PRODUCTION
OF OILS AND FATS
Over
the last 50 years there have been significant
changes to food production and processing with
a trend away from animal fats towards [healthier]
vegetable oils. The changes have been reflected
by large scale production of oilseeds and improved
processing technology.
Global
production of vegetable oils and fats is currently
of the order of
110 million tones per year, almost double the
level of 20 years ago. This growth is expected
to continue, notably in developing countries,
driven by population increase as well as increasing
personal disposable income. Regional demand is
satisfied by a combination of:
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Crushing and processing of locally produced seeds
• Crushing and processing of imported seeds
• Processing of imported crude and RBD [“refined,
bleached, deodorised”] oils.
The
graph below shows production of the 17 principal
oils and fats expressed as five-year averages
over the periods 1976 - 2020 and 1981 - 2020 respectively.
The
importance of the graph is that in the developed
countries, for example Europe, shows relatively
low growth - in line with Europe’s relatively
stable population.
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